Hierarchical CO2-protective shell for highly efficient oxygen reduction reaction
نویسندگان
چکیده
منابع مشابه
Hierarchical CO2-protective shell for highly efficient oxygen reduction reaction
The widespread application of intermediate-temperature solid oxide fuel cells is mainly being hurdled by the cathode's low efficiency on oxygen reduction reaction and poor resistance to carbon dioxide impurity. Here we report the fabrication of a hierarchical shell-covered porous cathode through infiltration followed by microwave plasma treatment. The hierarchical shell consists of a dense thin...
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Highly efficient and chemically compatible LnxSr1-xCoO3-delta (Ln = La, Sm, Gd, ...)/Co3O4 electrocatalysts for oxygen reduction reaction are presented and the very low cathode polarization resistances and excellent performances implied their promising application for developing intermediate-temperature solid oxide fuel cells (SOFCs), as well as potential application for oxygen separation membr...
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To increase Pt utilization for oxygen reduction reaction (ORR) in fuel cells, reducing particle sizes of Pt is a valid way. However, poisoning or surface oxidation limits the smallest size of Pt particles at 2.6 nm with a low utility of 20%. Here, using density functional theory calculations, we develop a core-shell Al13@Pt42 cluster as a catalyst for ORR. Benefit from alloying with Al in this ...
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Heterostructures of oxides have been widely investigated in optical, catalytic and electrochemical applications, because the heterostructured interfaces exhibit pronouncedly different transport, charge, and reactivity characteristics compared to the bulk of the oxides. Here we fabricated a three-dimensional (3D) heterostructured electrode with a concentration gradient shell. The concentration g...
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ژورنال
عنوان ژورنال: Scientific Reports
سال: 2012
ISSN: 2045-2322
DOI: 10.1038/srep00327